Anda belum login :: 22 Jul 2024 21:52 WIB
Detail
ArtikelReactions of Cisplatin Hydrolytes With Thiols. 3: Reactions of cis-[Pt(15nh3)2(H2o)2]2+ With Glutathione  
Oleh: Hadi, Sutopo
Jenis: Article from Journal - ilmiah nasional - terakreditasi DIKTI
Dalam koleksi: Makara Seri Sains vol. 10 no. 1 (2006), page 19-23.
Topik: 15N NMR; Glutathione; Cisplatin Hydrolytes
Ketersediaan
  • Perpustakaan Pusat (Semanggi)
    • Nomor Panggil: MM65.2
    • Non-tandon: 1 (dapat dipinjam: 0)
    • Tandon: tidak ada
    Lihat Detail Induk
Isi artikelThe reaction of cis-[Pt(’5NH3)2(H2O)2]2’~ (3) with glutathione (GSH) was investigated in aqueous solution. In this reaction, the ammine in the platinum complex formed was liberated. Surprisingly two chelate rings were observed, six¬membered-S,O-chelate ring complex cis-[Pt(~NH3)2(SG-S,O) (7) and five-membered-S,N-chelate ring complex cis¬[Pt(’5NH3)2(SG-S,N)] (8). The bis (thiolate) platinum(II) complex, cis-[Pt(’5NH3)2(SG)2] (9) was always present in this reaction in any mole ratio used. The dinuclear sulphur-bridged complex (10), giving a broad peak in ‘N NMR, was only present in very tiny amounts.
Opini AndaKlik untuk menuliskan opini Anda tentang koleksi ini!

Kembali
design
 
Process time: 0.015625 second(s)