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ArtikelA Molecule Carrier  
Oleh: Wong, K.L. ; Pawin, G. ; Kwon, K-Y ; Lin, X. ; Jiao, T ; Solanki, U. ; Fawcett, R.H.J ; Bartels, L ; Stolbov, S. ; Rahman, T.S.
Jenis: Article from Bulletin/Magazine
Dalam koleksi: SCIENCE (keterangan: ada di Proquest) vol. 315 no. 5817 (Mar. 2007), page 1391.
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  • Perpustakaan FK
    • Nomor Panggil: S01.K.2007.03
    • Non-tandon: 1 (dapat dipinjam: 0)
    • Tandon: tidak ada
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Isi artikelWe found that anthraquinone diffuses along a straight line across a flat, highly symmetric (u(111) surface. It can also reversibly attach one or two CO2 molecules as "cargo" and act as a "molecule carrier," thereby transforming the diffusive behavior of the CO2 molecules from isotropic to linear. Density functional theory calculations indicated a substrate-mediated attraction of -0.12 electron volt (eV). Scanning tunneling microscopy revealed individual steps of the molecular complex on its diffusion pathway, with increases of -0.03 and -0.02 eV in the diffusion barrier upon attachment of the first and second CO2 molecule, respectively.
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