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Supramolecular Interactions of Terpyridine - Derived Cores of Metallomesogen Precursors (on International Journal of Molecular Sciences Oct 2013 Vol.14 No.10, 20729-20743)
Bibliografi
Author:
Lee, Young Hoon
;
Harrowfield, Jack M.
;
Shin, Jong Won
;
Won, Mi Seon
;
Rukmini, Elisabeth
;
Hayami, Shinya
;
Min, Kil Sik
;
Kim, Yang
Topik:
Hirshfeld Surfaces
;
Crystal Structures
;
Labile interactions
;
Functionalised terpyridines
;
Spin Crossover
;
JABFUNG-ELR-2018-01
Bahasa:
(ID )
Edisi:
Int. J. Mol. Sci. 2013, 14(10), 20729-20743
Penerbit:
Multidisciplinary Digital Publishing Institute (MDPI)
Tempat Terbit:
Basel, Switzerland
Tahun Terbit:
2013
Jenis:
Article - diterbitkan di jurnal ilmiah internasional
Fulltext:
Young Hoon Lee; Jack M. Harrowfield; Jong Won Shin; Mi Seon Won; Elisabeth Rukmini; Shinya Hayami; Kil Sik Min; and Yang Kim.pdf
(557.07KB;
7 download
)
Abstract
Use of Hirshfeld surfaces calculated from crystal structure determinations on various transition metal ion complexes of three terpyridine ligands carrying trimethoxyphenyl substituents has enabled an assessment of the contribution made by the ligand components to the interactions determining the lattice structures, interactions expected also to be present in metallomesogens derived from similar ligands. The form of the link joining the trimethoxyphenyl substituent to the 4' position of 2,2';6',2''-terpyridine is of some importance. In the case of the Co(II) complexes of two of the ligands, their spin-crossover characteristics can be rationalised in terms of the different interactions seen in their lattices.
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