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Surface Trapping of Atoms and Molecules with Dipole Rings
Oleh:
Dil, Hugo
;
Lobo-Checa, Jorge
;
Laskowski, Robert
;
Blaha, Peter
Jenis:
Article from Bulletin/Magazine
Dalam koleksi:
SCIENCE (keterangan: ada di Proquest) vol. 319 no. 5871 (Mar. 2008)
,
page 1824-1826.
Ketersediaan
Perpustakaan FK
Nomor Panggil:
S01.K.2008.03
Non-tandon:
1 (dapat dipinjam: 0)
Tandon:
tidak ada
Lihat Detail Induk
Isi artikel
The trapping of single molecules on surfaces without the formation of strong covalent bonds is a prerequisite for molecular recognition and the exploitation of molecular function. On nanopatterned surfaces, molecules may be selectively trapped and addressed. In a boron nitride nanomesh formed on Rh(111), the pattern consisted of holes 2 nanometers in diameter on a hexagonal superlattice, separated by about 3 nanometers. The trapping was further investigated with density functional theory and the photoemission of adsorbed xenon, where the holes were identified as regions of low work function. The analysis showed that the trapping potential was localized at the rims of the holes.
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